aluminium dodecyl sulfate trihydrate [al(ds)3].3h2o: an efficient lewis acid-surfactant-combined catalyst for synthesis of 1,8-dioxo-octahydroxanthens and 1,8-dioxo-decahydroacridines

نویسندگان

s. firoozi

چکیده

an efficient synthesis of 1, 8-dioxo-octahydroxanthens and 1, 8-dioxo-decahydroacridines from the reaction of 5,5-dimethyl-1,3-cyclohexanedione (dimedone) with aromatic aldehydes bearing electron-donating or withdrawing substituents either in the presence or absence of primary amines has been described in a single pot using a catalytic amounts of aluminum tris (dodecyl sulfate) trihydrate [al(ds)3·3h2o] as a lewis acid-surfactant-combined catalyst. both reactions occurred at 80 oc. 1, 8-dioxo-octahydroxanthens has been synthesized under solvent-free conditions and water is used as a green solvent for the synthesis of 1, 8-dioxo-decahydroacridines. this methodology offers several advantages such as very simple work-up procedure, short reaction times, and mild reaction conditions.

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عنوان ژورنال:
iranian journal of science and technology (sciences)

ISSN 1028-6276

دوره 39

شماره 2 2015

کلمات کلیدی
[ ' a l u m i n i u m d o d e c y l s u l f a t e t r i h y d r a t e ' , ' l e w i s a c i d ' , ' l e w i s a c i d s u r f a c t a n t c a t a l y s t ' , ' x a n t h e n e s ' , 1 , 8 , ' d i o x o ' , ' o c t a h y d r o x a n t h e n s ' , ' a c r i d i n e d i o n e s ' , 1 , 8 , ' d i o x o ' , ' d e c a h y d r o a c r i d i n e s ' , ' m u l t i c o m p o n e n t r e a c t i o n s ' , ' g r e e n c h e m i s t r y ' ]

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