aluminium dodecyl sulfate trihydrate [al(ds)3].3h2o: an efficient lewis acid-surfactant-combined catalyst for synthesis of 1,8-dioxo-octahydroxanthens and 1,8-dioxo-decahydroacridines
نویسندگان
چکیده
an efficient synthesis of 1, 8-dioxo-octahydroxanthens and 1, 8-dioxo-decahydroacridines from the reaction of 5,5-dimethyl-1,3-cyclohexanedione (dimedone) with aromatic aldehydes bearing electron-donating or withdrawing substituents either in the presence or absence of primary amines has been described in a single pot using a catalytic amounts of aluminum tris (dodecyl sulfate) trihydrate [al(ds)3·3h2o] as a lewis acid-surfactant-combined catalyst. both reactions occurred at 80 oc. 1, 8-dioxo-octahydroxanthens has been synthesized under solvent-free conditions and water is used as a green solvent for the synthesis of 1, 8-dioxo-decahydroacridines. this methodology offers several advantages such as very simple work-up procedure, short reaction times, and mild reaction conditions.
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عنوان ژورنال:
iranian journal of science and technology (sciences)ISSN 1028-6276
دوره 39
شماره 2 2015
کلمات کلیدی
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